Volume 434
Main Index

Issue 1, Pages 1-132 (4 August 1992)

Author index Page C13

Synthesis and X-ray crystal structure of trans-[MoF(CCH2 tBu)(Ph2PCH2CH2PPh2)2][BF4], a paramagnetic alkylidynefluorocomplex Pages C6-C9 M. Amélia N.D.A. Lemos, Armando J. L. Pombeiro, David L. Hughes and, Raymond L. Richards

Synthesis, characterisation and molecular structure of [Ru5C(CO)15(HgCF3)(CF3CO2)] Pages C10-C12 Brian F. G. Johnson, Jack Lewis, Paul R. Raithby, Vijay P. Saharan, Wing Tak Wong

Base-free cationic 14-electron alkyls of Ti, Zr and Hf as polymerisation catalysts: A comparison Pages C1-C5 Manfred Bochmann, Simon J. Lancaster

Mercuriation of 3,4,5-trimethoxybenzoic acid. Synthesis of derivatives of the mercuriation product and crystal and molecular structure of PPh3(CH2Ph)][HgCl{C6H(CO2)-6-(OMe)3-2,3,4}] Pages 1-9 José Vicente, José-Antonio Abad, Antonia Sandoval, Peter G. Jones

Ligand redistribution reactions of Me2Ga(C5H5) and MeGa(C5H5)2 Pages 11-17 O. T. BeachleyJr., T. L. RoysterJr., J. R. Arhar

Ab initio study of the molecule C6H5SiH3 and the molecular anion C6H5SiH2−: Geometries and rotational barriers Pages 19-33 Fabio Ramondo

Reaktionen subvalenter verbindungen des siliciums mit benzol und mit biphenyl Pages 35-44 Frank Huppmann, Walter Maringgele, Thomas Kottke, Anton Meller

Multinuclear NMR spectroscopic studies of some organometallic N-substituted anilines Pages 45-52 Brian K. Barr, Amy J. Herman, Lori K. Myers, Pamela I. Young, Charles D. SchaefferJr., Hilary J. Eppley, Julie C. Otter and, Claude H. Yoder

Reactivity of main-group-transition-metal bonds : X. The kinetics of iodination of compounds containing one, two, three or four tin-cobalt bonds Pages 53-56 John R. Chipperfield, David E. Webster, Halimahton Yusof

Die kristallstruktur des tris(dimethylthiophosphinyl)phosphans Pages 57-61 Manfred Scheer, Peter G. Jones

Einfluß verschiedenartig substituierter cyclopentadienylliganden auf die chemie schwefelreicher organometallkomplexe mit metallen der 6. Nebengruppe Pages 63-78 Henri Brunner, Roland Graßl, Walter Meier, Joachim Wachter, Bernd Nuber and, Manfred L. Ziegler

Gehinderte ligandbewegungen in übergangsmetallkomplexen : XLI. Das dynamische Verhalten von 1,2-Bis(dimethylphosphino)ethan-dicarbonyl-(η4 -dien)-wolfram(O) Pages 79-87 Saim Özkar, Ceyhan Kayran, Cornelius G. Kreiter

One-electron reduction of the iron carbene complexes [Fe(CP)(CO)2(=C(OMe)R)]+ (R = H or Me) and hydrogen-atom vs. alkyl-radical transfer in the 19-electron intermediates Pages 89-96 Sylvain Nlate, Véronique Guerchais, Claude Lapinte

Functionalization of chlorobenzenes via their CpFe+ salts: A synthesis of substituted diphenyl ethers Pages 97-114 Richard C. Cambie, Sally J. Janssen, Peter S. Rutledge, Paul D. Woodgate

The constitution of a ferrocenyl diketone: Solution and solid state NMR spectroscopy. Crystal structure of 1-ferrocenyl-3-hydroxybut-2-en-1-one Pages 115-121 William Bell, Joe A. Crayston, Christopher Glidewell, Muhammed A. Mazid and, Michael B. Hursthouse

Mercury-bridged transition-metal clusters. Synthesis of pentanuclear Ru3HgM (M = Mo, W, or Co) clusters and X-ray structure of [(Ru3(μ3,η2-ampy)(CO)9)-(μ3-Hg)Co(CO)4] (Hampy = 2-amino-6-methylpyridine) Pages 123-132 Pedro L. Andreu, Javier A. Cabeza, Angela Llamazares, Víctor Riera, Santiago García-Granda and, Juan F. Van der Maelen

Issue 2, Pages 133-259 (11 August 1992)

Author index Page C17

Announcement Page C16

Chemistry of the platinum group metals: Recent developments : F.R. Hartley (Ed.), Elsevier, Amsterdam, 1991, 642 pages. $27450. Dfl 480. ISBN 0-444-88189-1 Pages C15-C16 D. M. P. Mingos

Carbonylation of B---H-boranes; evidence for a Fischer—Tropsch type reaction Pages 133-141 Mohamed Yalpani, Roland Köster

Primary amide and amine complexes of gallium and indium: X-ray crystal structures of [Me2Ga(μ-NH(tBu))]2, Me3Ga · NH2(tBu) and Me3In · NH2(tBu). Pages 143-150 David A. Atwood, Richard A. Jones, Alan H. Cowley, Simon G. Bott and, Jerry L. A twood

3,5-Di-tert-butylthiobenzoyltriphenylsilane: A versatile spin trapping agent Pages 151-158 Angelo Alberti, Massimo Benaglia

Darstellung und eigenschaften trifluormethylsubstituierter stannane, (CF3)nSnH4−n (n = 1–3) Pages 159-168 R. Eujen, N. Jahn, U. Thurmann

Übergangsmetall-stannyl-komplexe : V. Darstellung der anionischen stannyl-komplexe k[(π-Aromat)(CO) 2CrSnPh3] und reaktion mit organozinnhalogeniden zu bis(stannyl)-komplexen (π-Aromat)(CO)2Cr(SnPh3)(SnR3) (π-Aromat = C6H6-nMen) Pages 169-179 Ulrich Schubert, Jürgen Schubert

Coordinated 2-halo-1,3,2-dioxaphosphorinane ligands : III. cis-Mo(CO)4{REP(OCH2CMe2CH2O)}2 (E = O, S, NH; R = alkyl, aryl or ER = Cl, Br) complexes: syntheses, spectroscopic studies and the molecular structures of the cis-Mo(CO)4{iPrEP(OCH2CMe2CH2O)}2 (E = O, NH) complexes Pages 181-199 Gary M. Gray, William Watt

Carbyne-carbyne coupling at a single metal center. Synthesis structure of bis(diethylamino)acetylene complexes of molybdenum(II) and tungsten(II) Pages 201-223 Alexander Constantin Filippou, Christian Völkl, Walter Grünleitner, Paul Kiprof

Synthesis and structure analysis of [(tBuC6H5)Mn(CO)3]ClO4 its reaction with some nucleophiles Pages 225-233 Eunheui Jeong, Young Keun Chung

The vacuum ultraviolet spectrum of [Mn2(CO)10] Pages 235-240 Antonio Márquez, Javier Fernández Sanz, Michel Gelizé and, Alain Dargelos

Coordination chemistry of [CH{P(S)Ph2}2]−: X-ray diffraction studies of S,S-chelate complexes of iridium and rhodium Pages 241-252 Jane Browning, Gordon W. Bushnell, Keith R. Dixon, Robert W. Hilts

Photochemical reactions of diphosphineplatinum(II) oxalate complexes Pages 253-259 Gordon K. Anderson, Gregg J. Lumetta, Jeffrey W. Siria

Issue 3, Pages 261-385 (18 August 1992)

Author index Pages C26-C27

Nucleophilic attack by isocyanides, phosphines and cyclohexenesulphide on the α-carbon of “side-on” bonded μ-σ : η2-(4e)-vinylidenes; formation of thioketene and thioaldehyde dimolybdenum complexes Pages C19-C25 Michael Bamber, Simon F. T. Froom, Michael Green, Michael Schulz, Helmut Werner

Subject index Pages C28-C32

Organotin compounds with 2,2′-biimidazole derivatives. The crystal structure of dibromo(N,N′-dimethyl-2,2′-biimidazole)dimethyltin(IV) Pages 261-268 C. López, A. Sánchez González, M. E. García, J. S. Casas, J. Sordo, R. Graziani, U. Casellato

Stereoselective hydrostannation: Synthesis and absolute configuration of (−)-menthyl 2,3-diphenyl-3-(trimethylstannyl) propanoates and derivatives Pages 269-285 J. C. Podestá, A. B. Chopa, L. C. Koll, S. D. Mandolesi

Synthese und charakterisierung von hydridotrispyrazolylborat-heterobimetall-komplexen mit Titan und Molybdän Pages 287-302 Junes Ipaktschi, Werner Sulzbach

Synthese und stereokontrollierte funktionalisierung von hydridotrispyrazolylborat-molybdän-dien-komplexen Pages 303-320 Junes Ipaktschi, Arno Hartmann, Roland Boese

Reactions of [WI2(CO)(NCMe)(η2-RC2R)2] (R = Me or Ph) with t-butylisonitrile Pages 321-328 Elaine M. Armstrong, Paul K. Baker, Tony Callow, Kevin R. Flower, Paul D. Jackson, Lisa M. Severs

Hydrogen bonds and conformations of α-carbinol derivatives of cyclopentadienyltricarbonyls of manganese and rhenium Pages 329-339 E. S. Shubina, A. N. Krylov, T. V. Timofeeva, Yu. T. Struchkov, A. G. Ginzburg, N. M. Loim, L. M. Epstein

[Tris(1-pyrazolyl)hydroborato]ruthenium chemistry: Preparation and reactions of {Ru(η3-HB[1-pyrazolyl]3)-(PPh3) (CO)(X)} (X = H, Cl). The X-ray crystal structure of {Ru(η3-HB[1-pyrazolyl3)(PPh3)(CO)(PMe3)}PF6 Pages 341-349 Ning-Yu Sun, Stephen J. Simpson

The synthesis and characterisation of an ortho-metallated carbeneruthenium(II) complex, containing a metallated N-benzyl substituent with a 6-membered metallate nucleus, crystal structure of [RH4)(PPh3)2] Pages 351-362 Mark A. Owen, Peter L. Pye, Brian Piggott, Mario V. Capparelli

Synthesis, crystal structures, and solution dynamics of some mono(2,4-dimethylpentadienyl) ruthenium(II) complexes Pages 363-385 Tito Lumini, David N. Cox, Raymond Roulet, Kurt Schenk